Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C

Harbi Tomah Al-Masri, Beshir M. Mohamed, Ziad Moussa, Mohamed H. Alkordi

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

Original languageEnglish
Pages (from-to)738-746
Number of pages9
JournalHelvetica Chimica Acta
Volume96
Issue number4
DOIs
Publication statusPublished - Apr 2013
Externally publishedYes

Keywords

  • Chromium complexes
  • Molybdenum complexes
  • Phosphinous amide
  • Tungsten complexes
  • X-Ray crystallography

ASJC Scopus subject areas

  • Catalysis
  • Biochemistry
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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