Speciation analysis of 129I, 137Cs, 232Th, 238U, 239Pu and 240Pu in environmental soil and sediment

Jixin Qiao, Violeta Hansen, Xiaolin Hou, Ala Aldahan, Göran Possnert

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

The environmental mobility and bioavailability of radionuclides are related to their physicochemical forms, namely species. We here present a speciation analysis of important radionuclides including 129I (also 127I), 137Cs, 232Th, 238U and plutonium isotopes ( 239Pu and 240Pu) in soil (IAEA-375) and sediment (NIST-4354) standard reference materials and two fresh sediment samples from Øvre Heimdalsvatnet Lake, Norway. A modified sequential extraction protocol was used for the speciation analysis of these samples to obtain fractionation information of target radionuclides. Analytical results reveal that the partitioning behaviour, and thus the potential mobility and bioavailability, are exclusively featured for the individual radionuclide. Iodine is relatively mobile and readily binds to organic matter, while plutonium is mainly bound to both organic matter and nitric acid leachable fractions. Thorium is predominated in nitric acid leachable fraction and caesium is primarily observed in nitric acid and aqua regia leachable fractions and residue. Our analytical results reveal that around 50% of uranium might still remain in the residue which could not be extracted with aggressive acid, namely, aqua regia.

Original languageEnglish
Pages (from-to)1698-1708
Number of pages11
JournalApplied Radiation and Isotopes
Volume70
Issue number8
DOIs
Publication statusPublished - Aug 2012

Keywords

  • Bioavailability
  • Mobility
  • Partitioning
  • Sediment
  • Sequential extraction
  • Soil

ASJC Scopus subject areas

  • Radiation

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