So-photoextrusion of 7-thiabicyclo[2.2.1]hept-2-ene 7-oxides

Carolin Thiemann, Thies Thiemann, Yuanqiang Li, Tsuyoshi Sawada, Yoshiaki Nagano, Masashi Tashiro

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21 Citations (Scopus)

Abstract

The photoextrusion of the SO-bridge of 7-thiabicyclo[2.2.1]hept-2-ene 7-oxides is discussed. An analysis of all the major by-products in the exemplary case of the photo reaction of 3a is given. The existence of intermediate dienes 4 has been established. Data on a comparative photoextrusion of an epithio-bridge of 7-thiabicyclo[2.2.1]-hept-2-ene (6) are provided.

Original languageEnglish
Pages (from-to)1886-1893
Number of pages8
JournalBulletin of the Chemical Society of Japan
Volume67
Issue number7
DOIs
Publication statusPublished - Jan 1 1994
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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