Preparation of oil sorbents by solvent-free grafting of cellulose cotton fibers

Khalid Jarrah, Soleiman Hisaindee, Mohammad H. Al-Sayah

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Abstract: Natural cellulose-based fibers, such as cotton, have been investigated as oil sorbent to remediate and recover oil spills. The unmodified fibers are hydrophilic and have a high capacity to absorb water. To circumvent this drawback, the hydrophobicity of fibers is usually enhanced by chemical modification using solution-based processes that produce significant amounts of chemical waste. In the present study, gas–solid solvent-free silylation reaction was used to graft alkyl groups on cotton fibers. The modified cotton fibers were characterized by IR-spectroscopy, TGA analysis and SEM–EDS. The degree of substitution varied between 0.1 and 0.3 per glucose residue. The ability of the fibers to remove oil from the surface of simulated sea-water was investigated and all the modified fibers have adsorption capacity at least five times that of unmodified cotton. To optimize the adsorption capacity, factors that affect oil adsorption were investigated, namely the effect of fiber–oil contact time, temperature, and length of the grafted alkyl chains. Cotton fibers grafted with dialkyl substituted silyl ethers, through solvent-free silylation reaction, were found to have the best adsorption capacity of ~ 18 g oil/g of modified cotton with a fiber–oil contact time of 10 min at 25 °C.

Original languageEnglish
Pages (from-to)4093-4106
Number of pages14
JournalCellulose
Volume25
Issue number7
DOIs
Publication statusPublished - Jul 1 2018

Keywords

  • Cotton
  • Gas–solid silyl reaction
  • Hydrophobicity
  • Modified cellulose
  • Oil pollution remediation

ASJC Scopus subject areas

  • Polymers and Plastics

Fingerprint

Dive into the research topics of 'Preparation of oil sorbents by solvent-free grafting of cellulose cotton fibers'. Together they form a unique fingerprint.

Cite this