New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations

Thomas G. Back, Ziad Moussa

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

Replacement of the 2-keto group of readily available di(endo-3-camphoryl) diselenide with oxime or O-benzoyloxime substituents, followed by conversion into the corresponding selenenyl triflates, produced highly effective chiral selenium electrophiles for the asymmetric oxyselenenylation of alkenes in the presence of methanol.

Original languageEnglish
Pages (from-to)3007-3009
Number of pages3
JournalOrganic Letters
Volume2
Issue number19
DOIs
Publication statusPublished - Sep 21 2000
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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